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ISO 11235:2023

Rubber compounding ingredients — Sulfenamide accelerators — Test methods
24 korr 2023

General information

60.60     24 korr 2023

ISO

ISO/TC 45/SC 3

International Standard

83.040.20  

anglisht   frëngjisht  

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Scope

This document specifies the methods to be used for the evaluation of sulfenamide accelerators:
—     MBTS: benzothiazyl disulphide;
—     CBS: N-cyclohexylbenzothiazole-2-sulfenamide;
—     TBBS: N-tert-butylbenzothiazole-2-sulfenamide;
—     DIBS: N,N'-diisopropylbenzothiazole-2-sulfenamide;
—     DCBS: N,N'-dicyclohexylbenzothiazole-2-sulfenamide;
—     MBS: N-oxydiethylenebenzothiazole-2-sulfenamide.
NOTE 1        Although MBTS is not a sulfenamide, it is the primary decomposition product of these accelerators and quantitatively determined by the method specified in 5.2.
The analytical methods are applicable for most commercial sulfenamide accelerators:
—     sulfenamides of primary amines (type I);
—     sulfenamides of unhindered secondary amines (type II);
—     sulfenamides of hindered secondary amines (type III).
NOTE 2        Classification and key properties of sulfenamide accelerators are described in Annex A.
The method (5.2) to determine purity by high performance liquid chromatography (HPLC) is the preferred method.

Life cycle

PREVIOUSLY

WITHDRAWN
ISO 11235:2016

NOW

PUBLISHED
ISO 11235:2023
60.60 Standard published
24 korr 2023